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This book systematically elucidates the latest breakthroughs in Grain Boundary Engineering (GBE) technology for addressing the critical industry challenge of intergranular stress corrosion cracking in key components of nuclear power plants. Focusing on austenitic stainless steels and nickel-based alloys, it provides an in-depth exploration of how precise grain boundary design and control fundamentally enhance material service performance and longevity under extreme operating conditions